martes, 5 de marzo de 2013

Voltamperometry of selective dissolution of binary homogeneous metallic alloy in solid/liquid-phase mass-transfer conditions

Una técnica voltamperométrica ayudó a resolver el problema existente en la disolución aniónica selectiva cinéticamente reversible de una aleación homogénea entre dos metales a relaciones comparables de masas transferidas de iones metálicos disueltos y átomos en fase sólida.

The problem of anodic kinetically reversible selective dissoln. of homogeneous metal A-B alloy at comparable rates of mass transfer of dissolved metal ions (in the liq. phase) and atoms A (in the solid phase) was solved.  The conditions of purely solid-phase diffusion mass transfer limitations during the selective ionization of an alloy system were established.  With the use of numerical simulation of the voltammetric process the role of potential sweep rate, content of an electroneg. component in an alloy, concn. of ions in soln. and diffusivity in contacting phases in the mixed kinetics of the process is established.

Kozaderov, Oleg A.; Vvedenskii, Aleksandr V.
Kondensirovannye Sredy i Mezhfaznye Granitsy (2011), 13(4), 452-459.

Ion-beam formation of the active surface of methanol oxidation electrocatalysts on the tantalum substrates

La actividad electrocatalítica en la oxidación electrolítica del metanol en un sustrato de tántalo es medida por una voltamperometría cíclica.



The active surfaces of electrocatalysts are formed by the ion-beam-assisted deposition of one of the rare-earth metals and platinum onto tantalum substrates from a neutral vapor fraction and the vacuum-arc discharge plasma of a pulsed ion source.  Deposited metal ions are used as agents to aid deposition.  The compn. and microstructure of the formed surface layers are investigated via SEM, electron probe microanal., electron backscatter diffraction, and Rutherford backscattering spectrometry.  Electrocatalytic activity in the electrochem. oxidn. of methanol, which underlies the operation of low-temp. fuel cells, is investigated via cyclic voltamperometry.

Poplavskii, V. V.; Stel'makh, T. S.; Matys, V. G.
Journal of Surface Investigation: X-Ray, Synchrotron and Neutron Techniques (2012), 6(5), 748-757

Influence of tetrakis(4'-decaoxyphenyl)porphyrin addition on electrochemical reduction of oxygen on Pt electrode in dimethylformamide

Para medir la influencia que tiene en la reducción electroquímica del oxígeno la adición de un compuesto en concreto (tetrakis(4'-decaoxyphenyl)porphyrin) se utilizó una técnica voltamperométrica cíclica compuesta por un electrodo de platino. Esta medición es posible gracias a que la corriente de reducción electroquímica del oxígeno es proporcional a la velocidad con la que rota el electrodo.


Popov, Ivan A.; Kuzmin, Sergey M.; Chulovskaya, Svetlana A.; Semeikin, Alexander S.; Parfenyuk, Vladimir I.
 Makrogeterotsikly (2012), 5(2), 131-135

Electrochemical corrosion of the Al87(Y, Dy)5Ni8 amorphous alloys

La corrosión electroquímica de un determinado compuesto de aluminio fue medida en el trabajo llevado a cabo por Boichishin, L. M.; Kovbuz, M. O.; Gertsik, O. M.; Kotur, B. Ya.; Nosenko, V. K., entre otras técnicas, por voltamperometría.

The parameters of electrochem. corrosion of aluminum amorphous Al87(Y,Dy)5Ni8 alloys in NaCl and HCl aq. solns. are investigated by electrochem. impedance spectroscopy, potentiometry, voltamperometry, and Kelvin-probe methods.  Complete and partial substitution of Y in Al87Y5Ni8 alloy with Dy causes the substantial change of structure of superficial oxide layer with lower protective properties of metallic surface.
Metallofizika i Noveishie Tekhnologii (2012), 34(11), 1585-1593

Evaluation of silver-infused polylactide films for inactivation of Salmonella and feline calicivirus in vitro and on fresh-cut vegetables

La introducción de plata en una película de polilactida se hizo con el objetivo de inactivar ciertas enfermedades como la salmonelosis. para comprobar la efectividad de este experimento se mide la migración de la plata en la película a través de una voltamperometría.

Aquí puede leerese el resumen del artículo:

There is a growing trend to develop packaging materials with an active role in guarantying that the quality and safety characteristics of packaged products will remain or improve from prepn. throughout shelf-life.In the present study, 0.001-1.0 wt.% silver ions were satisfactorily incorporated into polylactide (PLA) films by a solvent casting technique.  Silver migration from the films was measured by voltamperometry and then correlated with its antimicrobial efficacy against Salmonella enterica and feline calicivirus (FCV), a human norovirus surrogate, by using the Japanese industrial std. (JIS Z 2801).  The PLA-silver films showed strong antibacterial and antiviral activity in vitro, with increasing effects at higher silver concns.  Moreover, results show that FCV was less susceptible to silver than Salmonella.  When films were applied on food samples, antibacterial and antiviral activity was reduced as compared to in vitro.  Antimicrobial activity was very much dependent on the food type and temp.  In lettuce samples incubated at 4 °C during 6 days, 4 log CFU of Salmonella was inactivated for films with 1.0 wt.% and no infectious FCV was reported under the same conditions.  On paprika samples, no antiviral effect was seen on FCV infectivity whereas films showed less antibacterial activity on Salmonella.

Martinez-Abad, A.; Ocio, M. J.; Lagaron, J. M.; Sanchez, G
International Journal of Food Microbiology (2013), 162(1), 89-94

A decrease in concentrations of heavy metals in aquatic medium during interactions with macrophytes

En este trabajo se miden las concentraciones de algunos metales pesados en un medio acuático por técnicas voltamperométricasm para cuantificar el decrecimiento de los mismos por reacción con macrófitos.

El artículo fue escrito por Poklonov, V. A.; Kotelevzev, S. A.; Shestakova, T. V. y Ostroumov, S. A. y publicado por la revista Ekologicheskaya Khimiya (2011), 20(4), 200-203